【金属或杂原子取代的烯基锆化合物的制备及其在有机合成中的应用】.pdf
Ph.D.Dissertation PreparationofMetallo-orHetero-atom Substituted Vinyl Zirconium Complexes and TheirApplicationsinOrganicSynthesis Ping Zhong Department of Chemistry Zhejiang University Hangzhou,P.R.
浙江大学理学博士学位论文 第二章(E)-烯基炭基锆及(Z)-α-锡基炭基锆的制备和应用)第一节(E)-烯基炭基锆的制备和应用)2引言2(E)-α、β-不饱和硫代酯的立体选择性合成(E)-α、β-不饱和硒代酯的立体选择性合成第二节(Z-α-锡基炭基锆的制备和应用.2引言.2(Z)-α-锡基-α、β-不饱和酯的立体选择性合成 2(Z)-α-锡基-α、β-不饱和醛的立体选择性合成 本章小结.
浙江大学理学博士学位论文 Abstract In the dissertation,the hydrozirconation of terminal alkynes,alkynyl acylzirconocenechlorideswithelectron affinity substanceswereinvestigated.organozirconium(IV) complexes,which were trapped with aryl or alkyl sulfenylchlorides,aryl 1oralkylsulfinylchloridesanddialkyl chlorop