[钯催化下有机高价碘化合物参与的反应研究]

【钯催化下有机高价碘化合物参与的反应研究】.pdf

Ph.D.Thesis The Study on the Palladium-Catalyzed Reactions with Hypervalent lodine Compounds Min Xia DepartmentofChemistry Zhejiang University Hangzhou,P.R.浙江大学博士论文 Index PartI:Introduction-Transition-MetalCatalyzedReactionsInvolvedwithHypervalent IodineCompounds PartII:Text Chapterone:CarbonylativeReactionwithIodonium Saltsunder theCatalystot PdCl(PPh)in thepresence of Chloform andAqueousAlkali ChapterTwo:Palladium-CatalyzedReactionswithIodoniumSalts浙江人学博十论文 Abstract Thetextdiscussesthereactionsinvolvedwithhypervalentiodine compounds and catalyzed by transitionalmetals:directcarbonylation of iodonium saltsintwo-phasemediaofaqueousalkaliandchloformwhichuses thecarbon monoxidegeneratedinsitu asthesource tocomplete thereactioninshort time andwi