【硒基或□基取代的金属有机试剂的制备及其在有机合成中的应用】.pdf
Ph.D.Dissertation Preparations ofSelenenyl and Sulfonyl-Substituted Organometallic Reagents and Their Applications in Organic Synthesis DehuiDuan Deparment of Chemistry Zhejiang University Hangzhou,P.R.
浙江大学理学博士学位论文 2引言2(Z)一β一卤代烯基矾的立体选择性合成.2(Z)一β一共轭炔烯基矾化合物的立体选择性合成 2(Z)-β一矾基取代的α,β一不饱和酮的立体选 择性合成2矾基取代的烯基锆的其它反应本章小结.第三章烯基锆的磺酰化反应一立体控制下合成(E)二取代的烯基矾 实验部分原料制备与实验操作化合物的表征参考文献博士期间已发表和待发表的论文 致谢.
浙江大学理学博士学位论文 Abstract In the dissertation, these were investigated of the preparations of selenium or sulfone-substituted alkylor ethenylorganometalliccompoundsandtheir applications in organic synthesis.Firstly, α-selenium-stabilized organozinc reagents were prepared by the insertion of metal zinc